Optimized Irreversibilities and Quartic Autocatalysis Chemical Reaction in A Wedge Flow
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Abstract
Entropy optimization in the dissipative flow of a viscous liquid with a chemical species of quartic autocatalysis inside wedge geometry is investigated in this study by executing the revised Buongiorno model using numerical simulations. To demonstrate the feasibility of this approach, an illustration of the well-known model of laminar flow in the wedge domain of a planar surface is provided. The term for nanoparticles amalgamation in the heat equation is omitted, which accounts for additional involvement brought on by the migration of the nanoparticles in relation to the fluid. In addition, the energy released by autocatalysis processes is assumed to be insignificant. The studied nanofluid and chemical reactions are believed to be in a local thermal balance state. The dimensionless equations for flow, temperature, and concentration (nanoparticle volume fraction) are formulated and solved numerically using the Runge-Kutta (RK-4) approach. Findings suggest that fluid concentration is lowered with a rise in Schmidt number while temperature is enhanced with an elevation in heat source parameter. Thermal distribution and entropy rate are improved with a larger approximation of the radiation variable. The wedge parameter \( m \) depicts contrary effects for liquid velocity and concentration boundary layers while entropy depletion is seen.
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References
- Nagendramma, V., Sreelakshmi, K., & Sarojamma, G. (2015). MHD heat and mass transfer flow over a stretching wedge with convective boundary condition and thermophoresis. Procedia Engineering, 127, 963–969.
[CrossRef] [Google Scholar] - Zhu, J. (2005). Generation of wedge-shaped dose distributions through dynamic multileaf collimator dose delivery. Journal of Applied Clinical Medical Physics, 6(3), 37–45.
[CrossRef] [Google Scholar] - Falkneb, V. M., & Skan, S. W. (1931). LXXXV. Solutions of the boundary-layer equations. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, 12(80), 865-896.
[CrossRef] [Google Scholar] - Vajravelu, K., & Nayfeh, J. (1992). Hydromagnetic convection at a cone and a wedge. International Communications in Heat and Mass Transfer, 19(5), 701–710.
[CrossRef] [Google Scholar] - Yih, K. A. (1998). Uniform suction/blowing effect on forced convection about a wedge: Uniform heat flux. Acta Mechanica, 128(3), 173–181.
[CrossRef] [Google Scholar] - Chamkha, A. J., Mujtaba, M., Quadri, A., & Issa, C. (2003). Thermal radiation effects on MHD forced convection flow adjacent to a non-isothermal wedge in the presence of a heat source or sink. Heat and Mass Transfer, 39(4), 305–312.
[CrossRef] [Google Scholar] - Ishak, A., Nazar, R., & Pop, I. (2007). Falkner-Skan equation for flow past a moving wedge with suction or injection. Journal of Applied Mathematics and Computing, 25(1), 67-83.
[CrossRef] [Google Scholar] - Ibrahim, W., & Tulu, A. (2019). Magnetohydrodynamic (MHD) boundary layer flow past a wedge with heat transfer and viscous effects of nanofluid embedded in porous media. Mathematical Problems in Engineering, 2019(1), 4507852.
[CrossRef] [Google Scholar] - Bano, N., Singh, B. B., & Sayyed, S. R. (2020). MHD heat transfer flow of Casson fluid with velocity and thermal slips over a stretching wedge in the presence of thermal radiation. Diffusion Foundations, 26, 1–22.
[CrossRef] [Google Scholar] - Waini, I., Ishak, A., & Pop, I. (2020). Transpiration effects on hybrid nanofluid flow and heat transfer over a stretching/shrinking sheet with uniform shear flow. Alexandria Engineering Journal, 59(1), 91–99.
[CrossRef] [Google Scholar] - Berrehal, H., Dinarvand, S., & Khan, I. (2022). Mass-based hybrid nanofluid model for entropy generation analysis of flow upon a convectively-warmed moving wedge. Chinese Journal of Physics, 77, 2603–2616.
[CrossRef] [Google Scholar] - Hussain, D., Asghar, Z., Zeeshan, A., & Alsulami, H. (2022). Analysis of sensitivity of thermal conductivity and variable viscosity on wall heat flux in flow of viscous fluid over a porous wedge. International Communications in Heat and Mass Transfer, 135, 106104.
[CrossRef] [Google Scholar] - Khan, W. A., & Pop, I. (2013). Boundary layer flow past a wedge moving in a nanofluid. Mathematical Problems in Engineering, 2013(1), 637285.
[CrossRef] [Google Scholar] - Rana, P., Gupta, S., & Gupta, G. (2023). FEM computations and Taguchi optimization in nonlinear radiative MHD MWCNT-MgO/EG hybrid nanoliquid flow and heat transfer over a 3D wedge surface. Case Studies in Thermal Engineering, 41, 102639.
[CrossRef] [Google Scholar] - Choi, S. U. (1995, November). Enhancing thermal conductivity of fluids with nanoparticles. In ASME international mechanical engineering congress and exposition (Vol. 17421, pp. 99-105). American Society of Mechanical Engineers.
[CrossRef] [Google Scholar] - Xuan, Y., & Roetzel, W. (2000). Conceptions for heat transfer correlation of nanofluids. International Journal of Heat and Mass Transfer, 43(19), 3701–3707.
[CrossRef] [Google Scholar] - Buongiorno, J. (2005). Convective transport in nanofluids. Journal of Heat Transfer, 128(3), 240–250.
[CrossRef] [Google Scholar] - Kameswaran, P. K., Shaw, S., Sibanda, P. V. S. N., & Murthy, P. V. S. N. (2013). Homogeneous–heterogeneous reactions in a nanofluid flow due to a porous stretching sheet. International journal of heat and mass transfer, 57(2), 465-472.
[CrossRef] [Google Scholar] - Hayat, T., Hussain, Z., Muhammad, T., & Alsaedi, A. (2016). Effects of homogeneous and heterogeneous reactions in flow of nanofluids over a nonlinear stretching surface with variable surface thickness. Journal of Molecular Liquids, 221, 1121-1127.
[CrossRef] [Google Scholar] - Zhang, C., Zheng, L., Zhang, X., & Chen, G. (2015). MHD flow and radiation heat transfer of nanofluids in porous media with variable surface heat flux and chemical reaction. Applied Mathematical Modelling, 39(1), 165–181.
[CrossRef] [Google Scholar] - Zhao, Q., Xu, H., & Tao, L. (2016). Homogeneous-heterogeneous reactions in boundary-layer flow of a nanofluid near the forward stagnation point of a cylinder. Journal of Heat Transfer, 139(3).
[CrossRef] [Google Scholar] - Chaudhary, M. A., & Merkin, J. H. (1995). A simple isothermal model for homogeneous-heterogeneous reactions in boundary-layer flow. I Equal diffusivities. Fluid Dynamics Research, 16(6), 311–333.
[CrossRef] [Google Scholar] - Xu, N. L., Xu, H., & Raees, A. (2018). Homogeneous-heterogeneous reactions in flow of nanofluids near the stagnation region of a plane surface: The Buongiorno’s model. International Journal of Heat and Mass Transfer, 125, 604-609.
[CrossRef] [Google Scholar] - Raizah, Z. A. S., Ahmed, S. E., & Aly, A. M. (2020). ISPH simulations of natural convection flow in E-enclosure filled with a nanofluid including homogeneous/heterogeneous porous media and solid particles. International Journal of Heat and Mass Transfer, 160, 120153.
[CrossRef] [Google Scholar] - Hayat, T., Rashid, M., Imtiaz, M., & Alsaedi, A. (2017). Nanofluid flow due to rotating disk with variable thickness and homogeneous-heterogeneous reactions. International Journal of Heat and Mass Transfer, 113, 96–105.
[CrossRef] [Google Scholar] - Sravanthi, C. S., Mabood, F., Nabi, S. G., & Shehzad, S. A. (2022). Heterogeneous and homogeneous reactive flow of magnetite-water nanofluid over a magnetized moving plate. Propulsion and Power Research, 11(2), 265–275.
[CrossRef] [Google Scholar] - Waqas, H., Khan, S. U., Khan, M. I., Alzahrani, F., & Qayyum, S. (2021). Study of homogeneous–heterogeneous reactions in bioconvection stagnation point slip flow of Walter’s-B nanofluid with nonlinear thermal radiation and activation energy. International Communications in Heat and Mass Transfer, 129, 105729.
[CrossRef] [Google Scholar] - Kumar, R., Kumar, R., Shehzad, S. A., & Sheikholeslami, M. (2018). Rotating frame analysis of radiating and reacting ferro-nanofluid considering Joule heating and viscous dissipation. International Journal of Heat and Mass Transfer, 120, 540–551.
[CrossRef] [Google Scholar] - Barleon, L., Casal, V., & Lenhart, L. (1991). MHD flow in liquid-metal-cooled blankets. Fusion Engineering and Design, 14(3-4), 401-412.
[CrossRef] [Google Scholar] - Müller, U., & Bühler, L. (2001). Magnetofluiddynamics in channels and containers. Springer Science & Business Media.
[CrossRef] [Google Scholar] - Murali, S., Hussam, W. K., & Sheard, G. J. (2021). Heat transfer enhancement in quasi-two-dimensional magnetohydrodynamic duct flows using repeated flow-facing wedge-shaped protrusions. International Journal of Heat and Mass Transfer, 171, 121066.
[CrossRef] [Google Scholar] - Waini, I., Ishak, A., & Pop, I. (2020). Flow and heat transfer of a hybrid nanofluid past a permeable moving surface. Chinese Journal of Physics, 66, 606-619.
[CrossRef] [Google Scholar] - Astanina, M. S., Sheremet, M. A., Oztop, H. F., & Abu-Hamdeh, N. (2018). MHD natural convection and entropy generation of ferrofluid in an open trapezoidal cavity partially filled with a porous medium. International Journal of Mechanical Sciences, 136, 493–502.
[CrossRef] [Google Scholar] - Raju, C. S. K., & Sandeep, N. (2016). Nonlinear radiative magnetohydrodynamic Falkner-Skan flow of Casson fluid over a wedge. Alexandria Engineering Journal, 55(3), 2045–2054.
[CrossRef] [Google Scholar] - Anantha Kumar, K., Ramana Reddy, J. V., Sugunamma, V., & Sandeep, N. (2018). Magnetohydrodynamic Cattaneo-Christov flow past a cone and a wedge with variable heat source/sink. Alexandria Engineering Journal, 57(1), 435–443.
[CrossRef] [Google Scholar] - Ali, L., Ali, B., Liu, X., Iqbal, T., Zulqarnain, R. M., & Javid, M. (2022). A comparative study of unsteady MHD Falkner–Skan wedge flow for non-Newtonian nanofluids considering thermal radiation and activation energy. Chinese Journal of Physics, 77, 1625–1638.
[CrossRef] [Google Scholar] - Bejan, A. (1996). Entropy generation minimization: The new thermodynamics of finite‐size devices and finite‐time processes. Journal of Applied Physics, 79(3), 1191–1218.
[CrossRef] [Google Scholar] - Bejan, A., & Kestin, J. (1983). Entropy generation through heat and fluid flow. Journal of Applied Mechanics, 50(2), 475.
[CrossRef] [Google Scholar] - Zhao, T., Hua, Y. C., & Guo, Z. Y. (2022). Irreversibility evaluation for transport processes revisited. International Journal of Heat and Mass Transfer, 189, 122699.
[CrossRef] [Google Scholar] - Malvandi, A., Ganji, D. D., Hedayati, F., & Rad, E. Y. (2013). An analytical study on entropy generation of nanofluids over a flat plate. Alexandria Engineering Journal, 52(4), 595-604.
[CrossRef] [Google Scholar] - Afridi, M. I., Qasim, M., & Shafie, S. (2017). Entropy generation in hydromagnetic boundary flow under the effects of frictional and Joule heating: Exact solutions. The European Physical Journal Plus, 132(9), 404.
[CrossRef] [Google Scholar] - Khan, M., Azam, M., & Alshomrani, A. S. (2017). Effects of melting and heat generation/absorption on unsteady Falkner-Skan flow of Carreau nanofluid over a wedge. International Journal of Heat and Mass Transfer, 110, 437–446.
[CrossRef] [Google Scholar] - Hayat, T., Shafique, M., Tanveer, A., & Alsaedi, A. (2017). Slip and Joule heating effects on radiative peristaltic flow of hyperbolic tangent nanofluid. International Journal of Heat and Mass Transfer, 112, 559–567.
[CrossRef] [Google Scholar] - Rehman, S., Hashim, Alqahtani, S., Ben Hadj Hassine, S., & Eldin, S. M. (2023). Thermohydraulic and irreversibility assessment of Power-law fluid flow within wedge shape channel. Arabian Journal of Chemistry, 16(3), 104475.
[CrossRef] [Google Scholar] - Rosseland, S. (1931). Astrophysik: Auf atomtheoretischer Grundlage. Springer.
[CrossRef] [Google Scholar] - Hashim, Rehman, S., Alqahtani, S., Alshehery, S., & Ben Moussa, S. (2023). A comprehensive physical insight of inclined magnetic field on the flow of generalized Newtonian fluid within a conduit with homogeneous-heterogeneous reactions. Arabian Journal of Chemistry, 16(5), 104633.
[CrossRef] [Google Scholar] - Nayak, M. K., Mabood, F., Dogonchi, A. S., & Khan, W. A. (2021). Electromagnetic flow of SWCNT/MWCNT suspensions with optimized entropy generation and cubic auto catalysis chemical reaction. International Communications in Heat and Mass Transfer, 120, 104996.
[CrossRef] [Google Scholar] - Khan, M. I., Khan, S. A., Hayat, T., Khan, M. I., & Alsaedi, A. (2019). Nanomaterial based flow of Prandtl-Eyring (non-Newtonian) fluid using Brownian and thermophoretic diffusion with entropy generation. Computer Methods and Programs in Biomedicine, 180, 105017.
[CrossRef] [Google Scholar] - Vajravelu, K., & Mukhopadhyay, S. (2015). Fluid flow, heat and mass transfer at bodies of different shapes: numerical solutions. Academic Press.
[CrossRef] [Google Scholar] - Mukhopadhyay, S. (2012). Effects of radiation and variable fluid viscosity on flow and heat transfer along a symmetric wedge. Journal of Applied Fluid Mechanics, 2(2), 29–34.
[CrossRef] [Google Scholar] - Mukhopadhyay, S., & Bhattacharyya, K. (2014). Boundary layer flow and heat transfer of a Casson fluid past a symmetric porous wedge with surface heat flux. Chinese Physics B, 23(4), 044702.
[CrossRef] [Google Scholar] - Watanabe, T. (1990). Thermal boundary layers over a wedge with uniform suction or injection in forced flow. Acta Mechanica, 83(3), 119–126.
[CrossRef] [Google Scholar] - Yacob, N. A., Ishak, A., & Pop, I. (2011). Falkner–Skan problem for a static or moving wedge in nanofluids. International Journal of Thermal Sciences, 50(2), 133–139.
[CrossRef] [Google Scholar] - Berrehal, H., Maougal, A., Hayat, T., & Alsaedi, A. (2018, December). On the analytic solution of magnetohydrodynamic (MHD) flow by a moving wedge in porous medium. In Defect and Diffusion Forum (Vol. 389, pp. 128-137). Trans Tech Publications Ltd.
[CrossRef] [Google Scholar] - Berrehal, H., & Maougal, A. (2019). Entropy generation analysis for multi-walled carbon nanotube (MWCNT) suspended nanofluid flow over wedge with thermal radiation and convective boundary condition. Journal of Mechanical Science and Technology, 33(1), 459-464.
[CrossRef] [Google Scholar] - Kuo, B. L. (2005). Heat transfer analysis for the Falkner–Skan wedge flow by the differential transformation method. International Journal of Heat and Mass Transfer, 48(23-24), 5036-5046.
[CrossRef] [Google Scholar] - Butt, A. S., Munawar, S., Ali, A., & Mehmood, A. (2012). Entropy generation in the Blasius flow under thermal radiation. Physica Scripta, 85(3), 035008.
[CrossRef] [Google Scholar] - Mansur, S., & Ishak, A. (2016). Unsteady boundary layer flow of a nanofluid over a stretching/shrinking sheet with a convective boundary condition. Journal of the Egyptian Mathematical Society, 24(4), 650-655. http://dx.doi.org/10.1016/j.joems.2015.11.004
[Google Scholar] - Grötzbach, G. (2013). Challenges in low-Prandtl number heat transfer simulation and modelling. Nuclear engineering and design, 264, 41-55.
[CrossRef] [Google Scholar]
Cite This Article
TY - JOUR AU - Rehman, Sohail PY - 2026 DA - 2026/04/16 TI - Optimized Irreversibilities and Quartic Autocatalysis Chemical Reaction in A Wedge Flow JO - ICCK Journal of Applied Mathematics T2 - ICCK Journal of Applied Mathematics JF - ICCK Journal of Applied Mathematics VL - 2 IS - 2 SP - 137 EP - 152 DO - 10.62762/JAM.2025.513035 UR - https://www.icck.org/article/abs/JAM.2025.513035 KW - viscous material KW - wedge flow KW - heat and mass transfer KW - chemical reaction KW - entropy mechanism AB - Entropy optimization in the dissipative flow of a viscous liquid with a chemical species of quartic autocatalysis inside wedge geometry is investigated in this study by executing the revised Buongiorno model using numerical simulations. To demonstrate the feasibility of this approach, an illustration of the well-known model of laminar flow in the wedge domain of a planar surface is provided. The term for nanoparticles amalgamation in the heat equation is omitted, which accounts for additional involvement brought on by the migration of the nanoparticles in relation to the fluid. In addition, the energy released by autocatalysis processes is assumed to be insignificant. The studied nanofluid and chemical reactions are believed to be in a local thermal balance state. The dimensionless equations for flow, temperature, and concentration (nanoparticle volume fraction) are formulated and solved numerically using the Runge-Kutta (RK-4) approach. Findings suggest that fluid concentration is lowered with a rise in Schmidt number while temperature is enhanced with an elevation in heat source parameter. Thermal distribution and entropy rate are improved with a larger approximation of the radiation variable. The wedge parameter \( m \) depicts contrary effects for liquid velocity and concentration boundary layers while entropy depletion is seen. SN - 3068-5656 PB - Institute of Central Computation and Knowledge LA - English ER -
@article{Rehman2026Optimized,
author = {Sohail Rehman},
title = {Optimized Irreversibilities and Quartic Autocatalysis Chemical Reaction in A Wedge Flow},
journal = {ICCK Journal of Applied Mathematics},
year = {2026},
volume = {2},
number = {2},
pages = {137-152},
doi = {10.62762/JAM.2025.513035},
url = {https://www.icck.org/article/abs/JAM.2025.513035},
abstract = {Entropy optimization in the dissipative flow of a viscous liquid with a chemical species of quartic autocatalysis inside wedge geometry is investigated in this study by executing the revised Buongiorno model using numerical simulations. To demonstrate the feasibility of this approach, an illustration of the well-known model of laminar flow in the wedge domain of a planar surface is provided. The term for nanoparticles amalgamation in the heat equation is omitted, which accounts for additional involvement brought on by the migration of the nanoparticles in relation to the fluid. In addition, the energy released by autocatalysis processes is assumed to be insignificant. The studied nanofluid and chemical reactions are believed to be in a local thermal balance state. The dimensionless equations for flow, temperature, and concentration (nanoparticle volume fraction) are formulated and solved numerically using the Runge-Kutta (RK-4) approach. Findings suggest that fluid concentration is lowered with a rise in Schmidt number while temperature is enhanced with an elevation in heat source parameter. Thermal distribution and entropy rate are improved with a larger approximation of the radiation variable. The wedge parameter \( m \) depicts contrary effects for liquid velocity and concentration boundary layers while entropy depletion is seen.},
keywords = {viscous material, wedge flow, heat and mass transfer, chemical reaction, entropy mechanism},
issn = {3068-5656},
publisher = {Institute of Central Computation and Knowledge}
}
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