The advancement of global sustainable agriculture is currently impeded by the dual challenges of energy-intensive industrial nitrogen fixation and the persistent accumulation of agro-environmental pollutants. Bioelectrocatalysis has emerged as a transformative solution to these issues by synergizing the exquisite selectivity of biological catalysts with the controllability of renewable electricity-driven systems. However, the practical deployment of bioelectrocatalytic technologies is fundamentally constrained by kinetic bottlenecks associated with interfacial electron transfer (ET) between biocatalysts and solid electrodes. This review systematically summarizes recent advances in bioelectro... More >