Titanium-based high-entropy alloys (HEAs) have emerged as promising solid-state hydrogen storage materials owing to their structural stability, tunable thermodynamics, and rapid kinetics. This review systematically examines the hydrogen storage behaviour of Ti-based HEAs across three structural categories: body-centered cubic (BCC) single-phase alloys, C14 Laves phase alloys, and multiphase systems containing CsCl-type structures. The high-entropy effect, severe lattice distortion, sluggish diffusion, and cocktail effect collectively enable these alloys to overcome key limitations of conventional materials, including difficult activation, poor reversibility, and insufficient cycling stabilit... More >