Dielectric and Ferroelectric Properties of Ba$_{0.85}$Ca$_{0.15}$Ti$_{0.9}$Zr$_{0.1}$O$_3$–Sr$_{0.7}$Bi$_{0.2}$TiO$_3$ Solid Solution
Research Article  ·  Published: 28 March 2026
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Journal of Advanced Electronic Materials
Volume 2, Issue 1, 2026: 20-24
Research Article Open Access

Dielectric and Ferroelectric Properties of Ba$_{0.85}$Ca$_{0.15}$Ti$_{0.9}$Zr$_{0.1}$O$_3$–Sr$_{0.7}$Bi$_{0.2}$TiO$_3$ Solid Solution

1 Department of Physics, Abdul Wali Khan University Mardan, Mardan 23200, KP, Pakistan
* Corresponding Author: Kainat Shah, [email protected]
Volume 2, Issue 1

Article Information

Abstract

In this work, \((1-x)\text{Ba}_{0.85}\text{Ca}_{0.15}\text{Ti}_{0.9}\text{Zr}_{0.1}\text{O}_{3} - x\text{Sr}_{0.7}\text{Bi}_{0.2}\text{TiO}_{3}\) (BCZT–SBT) ceramics with \( x = 0 \) and \( x = 0.025 \) were prepared through the conventional solid-state route. The samples were calcined at \(1200\,^{\circ}\text{C}\) for \(6\,\text{h}\), then re-milled, pressed into pellets, and sintered at \(1325\,^{\circ}\text{C}\) for \(6\,\text{h}\). XRD patterns indicate the formation of a cubic perovskite structure. A small decrease in lattice parameter is observed upon introducing SBT (\(a\) decreases from \(4.0176\,\text{Å}\) to \(4.0149\,\text{Å}\)), accompanied by a slight reduction in unit-cell volume (\(64.85\,\text{Å}^3\) to \(64.72\,\text{Å}^3\)). \(\varepsilon_r\) increases strongly with \( x = 0.025 \): at \(1\,\text{MHz}\), \(\varepsilon_r\) rises from 1057 (\( x = 0 \)) to 2175 (\( x = 0.025 \)), while \(\tan\delta\) remains low (0.034–0.037). Ferroelectric measurements at \(30\,\text{kV/cm}\) show an increase in maximum polarization from \(11.06\,\mu\text{C/cm}^2\) (\( x = 0 \)) to \(23.5\,\mu\text{C/cm}^2\) (\( x = 0.025 \)), with the coercive field decreasing from \(6.9\,\text{kV/cm}\) to \(5.1\,\text{kV/cm}\).

Graphical Abstract

Dielectric and Ferroelectric Properties of Ba$_{0.85}$Ca$_{0.15}$Ti$_{0.9}$Zr$_{0.1}$O$_3$–Sr$_{0.7}$Bi$_{0.2}$TiO$_3$ Solid Solution

Keywords

BCZT SBT dielectric properties ferroelectric properties

Data Availability Statement

Data will be made available on request.

Funding

This work was supported without any funding.

Conflicts of Interest

The authors declare no conflicts of interest.

AI Use Statement

The authors declare that generative AI was used solely for language editing and grammatical refinement during the preparation of this manuscript. The AI tool utilized was ChatGPT. The authors carefully reviewed and verified all AI-assisted revisions and take full responsibility for the accuracy, originality, and integrity of the content.

Ethical Approval and Consent to Participate

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Cite This Article

APA Style
Shah, K., & Ali, A. (2026). Dielectric and Ferroelectric Properties of Ba0.85Ca0.15Ti0.9Zr0.1O3–Sr0.7Bi0.2TiO3 Solid Solution. Journal of Advanced Electronic Materials, 2(1), 20–24. https://doi.org/10.62762/JAEM.2026.678918
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TY  - JOUR
AU  - Shah, Kainat
AU  - Ali, Asif
PY  - 2026
DA  - 2026/03/28
TI  - Dielectric and Ferroelectric Properties of Ba$_{0.85}$Ca$_{0.15}$Ti$_{0.9}$Zr$_{0.1}$O$_3$–Sr$_{0.7}$Bi$_{0.2}$TiO$_3$ Solid Solution
JO  - Journal of Advanced Electronic Materials
T2  - Journal of Advanced Electronic Materials
JF  - Journal of Advanced Electronic Materials
VL  - 2
IS  - 1
SP  - 20
EP  - 24
DO  - 10.62762/JAEM.2026.678918
UR  - https://www.icck.org/article/abs/JAEM.2026.678918
KW  - BCZT
KW  - SBT
KW  - dielectric properties
KW  - ferroelectric properties
AB  - In this work, \((1-x)\text{Ba}_{0.85}\text{Ca}_{0.15}\text{Ti}_{0.9}\text{Zr}_{0.1}\text{O}_{3} - x\text{Sr}_{0.7}\text{Bi}_{0.2}\text{TiO}_{3}\) (BCZT–SBT) ceramics with \( x = 0 \) and \( x = 0.025 \) were prepared through the conventional solid-state route. The samples were calcined at \(1200\,^{\circ}\text{C}\) for \(6\,\text{h}\), then re-milled, pressed into pellets, and sintered at \(1325\,^{\circ}\text{C}\) for \(6\,\text{h}\). XRD patterns indicate the formation of a cubic perovskite structure. A small decrease in lattice parameter is observed upon introducing SBT (\(a\) decreases from \(4.0176\,\text{Å}\) to \(4.0149\,\text{Å}\)), accompanied by a slight reduction in unit-cell volume (\(64.85\,\text{Å}^3\) to \(64.72\,\text{Å}^3\)). \(\varepsilon_r\) increases strongly with \( x = 0.025 \): at \(1\,\text{MHz}\), \(\varepsilon_r\) rises from 1057 (\( x = 0 \)) to 2175 (\( x = 0.025 \)), while \(\tan\delta\) remains low (0.034–0.037). Ferroelectric measurements at \(30\,\text{kV/cm}\) show an increase in maximum polarization from \(11.06\,\mu\text{C/cm}^2\) (\( x = 0 \)) to \(23.5\,\mu\text{C/cm}^2\) (\( x = 0.025 \)), with the coercive field decreasing from \(6.9\,\text{kV/cm}\) to \(5.1\,\text{kV/cm}\).
SN  - 3070-5649
PB  - Institute of Central Computation and Knowledge
LA  - English
ER  - 
BibTeX Format
Compatible with LaTeX, BibTeX, and other reference managers
@article{Shah2026Dielectric,
  author = {Kainat Shah and Asif Ali},
  title = {Dielectric and Ferroelectric Properties of Ba\$\_{0.85}\$Ca\$\_{0.15}\$Ti\$\_{0.9}\$Zr\$\_{0.1}\$O\$\_3\$–Sr\$\_{0.7}\$Bi\$\_{0.2}\$TiO\$\_3\$ Solid Solution},
  journal = {Journal of Advanced Electronic Materials},
  year = {2026},
  volume = {2},
  number = {1},
  pages = {20-24},
  doi = {10.62762/JAEM.2026.678918},
  url = {https://www.icck.org/article/abs/JAEM.2026.678918},
  abstract = {In this work, \((1-x)\text{Ba}\_{0.85}\text{Ca}\_{0.15}\text{Ti}\_{0.9}\text{Zr}\_{0.1}\text{O}\_{3} - x\text{Sr}\_{0.7}\text{Bi}\_{0.2}\text{TiO}\_{3}\) (BCZT–SBT) ceramics with \( x = 0 \) and \( x = 0.025 \) were prepared through the conventional solid-state route. The samples were calcined at \(1200\,^{\circ}\text{C}\) for \(6\,\text{h}\), then re-milled, pressed into pellets, and sintered at \(1325\,^{\circ}\text{C}\) for \(6\,\text{h}\). XRD patterns indicate the formation of a cubic perovskite structure. A small decrease in lattice parameter is observed upon introducing SBT (\(a\) decreases from \(4.0176\,\text{Å}\) to \(4.0149\,\text{Å}\)), accompanied by a slight reduction in unit-cell volume (\(64.85\,\text{Å}^3\) to \(64.72\,\text{Å}^3\)). \(\varepsilon\_r\) increases strongly with \( x = 0.025 \): at \(1\,\text{MHz}\), \(\varepsilon\_r\) rises from 1057 (\( x = 0 \)) to 2175 (\( x = 0.025 \)), while \(\tan\delta\) remains low (0.034–0.037). Ferroelectric measurements at \(30\,\text{kV/cm}\) show an increase in maximum polarization from \(11.06\,\mu\text{C/cm}^2\) (\( x = 0 \)) to \(23.5\,\mu\text{C/cm}^2\) (\( x = 0.025 \)), with the coercive field decreasing from \(6.9\,\text{kV/cm}\) to \(5.1\,\text{kV/cm}\).},
  keywords = {BCZT, SBT, dielectric properties, ferroelectric properties},
  issn = {3070-5649},
  publisher = {Institute of Central Computation and Knowledge}
}

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