Multiphysics CFD and Electrochemical Assessment of Silicon Carbide (SiC) Heat Exchangers for Corrosive Waste-heat Recovery in Process Industries
Article Information
Abstract
Corrosive waste-heat recovery systems suffer material degradation, performance loss and high maintenance when conventional metallic heat exchangers face chloride-, carbonate- and sulfur-bearing condensates. This study presents a multiphysics CFD-electrochemical assessment of silicon carbide (SiC) for heat exchangers, via a 3D shell-and-tube model in COMSOL Multiphysics coupling turbulent flow, conjugate heat transfer, species transport and electrochemical corrosion. The thermal model considered high-pressure ammonia (tube side) and pressurized water (shell side); the corrosion model represented a flue-gas condensate/electrolyte containing Cl\(^-\), NH\(_4^+\), HCO\(_3^-\), CO\(_3^{2-}\), HSO\(_3^-\)/SO\(_4^{2-}\) and NO\(_3^-\) at the wetted surface, with electrochemical behavior resolved via secondary/tertiary current-distribution (Nernst–Planck/Butler–Volmer) formulations. Base-case results gave heat-transfer coefficients of 620 vs. 420 W m\(^{-2}\) K\(^{-1}\) (47.6% improvement), a pressure-drop reduction from 2.63 to 1.92 Pa, and a thermal–hydraulic performance factor of 1.64 (SiC vs. stainless steel). Electrochemical simulations predicted lower localized current density and corrosion flux for SiC than stainless steel under the same electrolyte chemistry, though as model-based comparative indicators rather than validated corrosion rates. Sensitivity screening showed SiC thermal conductivity, wall roughness, electrolyte conductivity and chloride concentration affect the magnitude of improvement, though the base-case trend remained favorable. The study offers a verified, literature-benchmarked framework for preliminary material screening, identifying experimental corrosion testing, temperature-dependent properties and thermo-electrochemical coupling as next steps before industrial adoption.
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References
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Cite This Article
TY - JOUR
AU - Effiom, Samuel Oliver
AU - Enoh, Maria Kaka Etete
AU - Akpan, Ukeme Enoh
AU - Effiom, Precious-Chibuzo
AU - Abam, Fidelis Ibiang
PY - 2026
DA - 2026/06/16
TI - Multiphysics CFD and Electrochemical Assessment of Silicon Carbide (SiC) Heat Exchangers for Corrosive Waste-heat Recovery in Process Industries
JO - International Journal of Thermo-Fluid Systems and Sustainable Energy
T2 - International Journal of Thermo-Fluid Systems and Sustainable Energy
JF - International Journal of Thermo-Fluid Systems and Sustainable Energy
VL - 2
IS - 2
SP - 81
EP - 100
DO - 10.62762/IJTSSE.2026.236790
UR - https://www.icck.org/article/abs/IJTSSE.2026.236790
KW - Silicon carbide
KW - CFD
KW - electrochemical corrosion
KW - waste-heat recovery
KW - shell-and-tube heat exchanger
KW - Nernst–Planck transport
AB - Corrosive waste-heat recovery systems suffer material degradation, performance loss and high maintenance when conventional metallic heat exchangers face chloride-, carbonate- and sulfur-bearing condensates. This study presents a multiphysics CFD-electrochemical assessment of silicon carbide (SiC) for heat exchangers, via a 3D shell-and-tube model in COMSOL Multiphysics coupling turbulent flow, conjugate heat transfer, species transport and electrochemical corrosion. The thermal model considered high-pressure ammonia (tube side) and pressurized water (shell side); the corrosion model represented a flue-gas condensate/electrolyte containing Cl\(^-\), NH\(_4^+\), HCO\(_3^-\), CO\(_3^{2-}\), HSO\(_3^-\)/SO\(_4^{2-}\) and NO\(_3^-\) at the wetted surface, with electrochemical behavior resolved via secondary/tertiary current-distribution (Nernst–Planck/Butler–Volmer) formulations. Base-case results gave heat-transfer coefficients of 620 vs. 420 W m\(^{-2}\) K\(^{-1}\) (47.6% improvement), a pressure-drop reduction from 2.63 to 1.92 Pa, and a thermal–hydraulic performance factor of 1.64 (SiC vs. stainless steel). Electrochemical simulations predicted lower localized current density and corrosion flux for SiC than stainless steel under the same electrolyte chemistry, though as model-based comparative indicators rather than validated corrosion rates. Sensitivity screening showed SiC thermal conductivity, wall roughness, electrolyte conductivity and chloride concentration affect the magnitude of improvement, though the base-case trend remained favorable. The study offers a verified, literature-benchmarked framework for preliminary material screening, identifying experimental corrosion testing, temperature-dependent properties and thermo-electrochemical coupling as next steps before industrial adoption.
SN - 3069-1877
PB - Institute of Central Computation and Knowledge
LA - English
ER -
@article{Effiom2026Multiphysi,
author = {Samuel Oliver Effiom and Maria Kaka Etete Enoh and Ukeme Enoh Akpan and Precious-Chibuzo Effiom and Fidelis Ibiang Abam},
title = {Multiphysics CFD and Electrochemical Assessment of Silicon Carbide (SiC) Heat Exchangers for Corrosive Waste-heat Recovery in Process Industries},
journal = {International Journal of Thermo-Fluid Systems and Sustainable Energy},
year = {2026},
volume = {2},
number = {2},
pages = {81-100},
doi = {10.62762/IJTSSE.2026.236790},
url = {https://www.icck.org/article/abs/IJTSSE.2026.236790},
abstract = {Corrosive waste-heat recovery systems suffer material degradation, performance loss and high maintenance when conventional metallic heat exchangers face chloride-, carbonate- and sulfur-bearing condensates. This study presents a multiphysics CFD-electrochemical assessment of silicon carbide (SiC) for heat exchangers, via a 3D shell-and-tube model in COMSOL Multiphysics coupling turbulent flow, conjugate heat transfer, species transport and electrochemical corrosion. The thermal model considered high-pressure ammonia (tube side) and pressurized water (shell side); the corrosion model represented a flue-gas condensate/electrolyte containing Cl\(^-\), NH\(\_4^+\), HCO\(\_3^-\), CO\(\_3^{2-}\), HSO\(\_3^-\)/SO\(\_4^{2-}\) and NO\(\_3^-\) at the wetted surface, with electrochemical behavior resolved via secondary/tertiary current-distribution (Nernst–Planck/Butler–Volmer) formulations. Base-case results gave heat-transfer coefficients of 620 vs. 420 W m\(^{-2}\) K\(^{-1}\) (47.6\% improvement), a pressure-drop reduction from 2.63 to 1.92 Pa, and a thermal–hydraulic performance factor of 1.64 (SiC vs. stainless steel). Electrochemical simulations predicted lower localized current density and corrosion flux for SiC than stainless steel under the same electrolyte chemistry, though as model-based comparative indicators rather than validated corrosion rates. Sensitivity screening showed SiC thermal conductivity, wall roughness, electrolyte conductivity and chloride concentration affect the magnitude of improvement, though the base-case trend remained favorable. The study offers a verified, literature-benchmarked framework for preliminary material screening, identifying experimental corrosion testing, temperature-dependent properties and thermo-electrochemical coupling as next steps before industrial adoption.},
keywords = {Silicon carbide, CFD, electrochemical corrosion, waste-heat recovery, shell-and-tube heat exchanger, Nernst–Planck transport},
issn = {3069-1877},
publisher = {Institute of Central Computation and Knowledge}
}
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Copyright © 2026 by the Author(s). Published by Institute of Central Computation and Knowledge. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/), which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.
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