Phenol Photodegradation over Ni/MCM-41: Effect of the Ni Incorporation Method
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Abstract
This study explores the synthesis and application of Ni-based photocatalysts supported on MCM-41 and Al-MCM-41 for phenol degradation. Three preparation methods were evaluated and compared: Chemical Vapor Deposition (CVD), Incipient Wet Impregnation (IWI), and Template Ion Exchange (TIE). The influence of the Si/Al ratio of 5 and 60 on phenol photodegradation was also examined. The results showed that the Ni/MCM-41 photocatalyst prepared by CVD achieved the highest degradation efficiency (97.28%), while the TIE method proved to be the most versatile overall. Notably, the TIE method was the only synthesis method capable of exhibiting photocatalytic activity in phenol degradation on all supports at different Si/Al ratios, unlike the materials prepared by CVD and IWI, which failed to degrade phenol in the presence of aluminum. These results indicate the TIE method as a novel synthesis method for the development of mesoporous photocatalysts with high photocatalytic activity in the degradation of phenol with different Si/Al ratios in the MCM-41 structure.
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References
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Cite This Article
TY - JOUR AU - Corona, Yulissa Aleli Esquivel AU - León, Laura Annette Romero De AU - Valdez, Elvia Valdez AU - Luna, Claudia Yolanda Valero AU - Frías, Alan Bañuelos AU - Perea, Leo Alvarado PY - 2026 DA - 2026/05/28 TI - Phenol Photodegradation over Ni/MCM-41: Effect of the Ni Incorporation Method JO - Journal of Chemical Engineering and Renewable Fuels T2 - Journal of Chemical Engineering and Renewable Fuels JF - Journal of Chemical Engineering and Renewable Fuels VL - 2 IS - 2 SP - 65 EP - 70 DO - 10.62762/JCERF.2026.349345 UR - https://www.icck.org/article/abs/JCERF.2026.349345 KW - Ni/MCM-41 KW - photodegradation of phenol KW - TIE KW - CVD KW - IWI AB - This study explores the synthesis and application of Ni-based photocatalysts supported on MCM-41 and Al-MCM-41 for phenol degradation. Three preparation methods were evaluated and compared: Chemical Vapor Deposition (CVD), Incipient Wet Impregnation (IWI), and Template Ion Exchange (TIE). The influence of the Si/Al ratio of 5 and 60 on phenol photodegradation was also examined. The results showed that the Ni/MCM-41 photocatalyst prepared by CVD achieved the highest degradation efficiency (97.28%), while the TIE method proved to be the most versatile overall. Notably, the TIE method was the only synthesis method capable of exhibiting photocatalytic activity in phenol degradation on all supports at different Si/Al ratios, unlike the materials prepared by CVD and IWI, which failed to degrade phenol in the presence of aluminum. These results indicate the TIE method as a novel synthesis method for the development of mesoporous photocatalysts with high photocatalytic activity in the degradation of phenol with different Si/Al ratios in the MCM-41 structure. SN - 3070-1058 PB - Institute of Central Computation and Knowledge LA - English ER -
@article{Corona2026Phenol,
author = {Yulissa Aleli Esquivel Corona and Laura Annette Romero De León and Elvia Valdez Valdez and Claudia Yolanda Valero Luna and Alan Bañuelos Frías and Leo Alvarado Perea},
title = {Phenol Photodegradation over Ni/MCM-41: Effect of the Ni Incorporation Method},
journal = {Journal of Chemical Engineering and Renewable Fuels},
year = {2026},
volume = {2},
number = {2},
pages = {65-70},
doi = {10.62762/JCERF.2026.349345},
url = {https://www.icck.org/article/abs/JCERF.2026.349345},
abstract = {This study explores the synthesis and application of Ni-based photocatalysts supported on MCM-41 and Al-MCM-41 for phenol degradation. Three preparation methods were evaluated and compared: Chemical Vapor Deposition (CVD), Incipient Wet Impregnation (IWI), and Template Ion Exchange (TIE). The influence of the Si/Al ratio of 5 and 60 on phenol photodegradation was also examined. The results showed that the Ni/MCM-41 photocatalyst prepared by CVD achieved the highest degradation efficiency (97.28\%), while the TIE method proved to be the most versatile overall. Notably, the TIE method was the only synthesis method capable of exhibiting photocatalytic activity in phenol degradation on all supports at different Si/Al ratios, unlike the materials prepared by CVD and IWI, which failed to degrade phenol in the presence of aluminum. These results indicate the TIE method as a novel synthesis method for the development of mesoporous photocatalysts with high photocatalytic activity in the degradation of phenol with different Si/Al ratios in the MCM-41 structure.},
keywords = {Ni/MCM-41, photodegradation of phenol, TIE, CVD, IWI},
issn = {3070-1058},
publisher = {Institute of Central Computation and Knowledge}
}
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