Bridging Refinery and Biorefinery: Modular Hydrotreating Pathways for Co-Processing Refractory Streams and Bio-Oils
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Abstract
Integrating biomass-derived oils into existing petroleum refineries is one of the fastest routes toward large-scale deployment of renewable liquid fuels. Yet co-processing bio-oils with refractory fossil streams, such as vacuum gas oil, cycle oils or coker gas oils, poses persistent hurdles: their high oxygen content, thermal instability and heteroatom-rich matrices accelerate catalyst fouling and drive hydrogen consumption. This Perspective argues that a modular hydrotreating strategy, in which tailored pretreatment, grading and active catalyst beds are arranged as interchangeable cartridges, offers a pragmatic path to bridge refinery and biorefinery operations. Drawing from recent continuous slurry hydrocracking, fixed-bed co-hydrotreating and digital-twin studies, it outlines how modular bed architecture, advanced slurry catalysts and adaptive control schemes could unlock feed flexibility while extending catalyst life by ~40% and cutting greenhouse-gas footprints by ~25% relative to standalone units. Finally, a short-term R&D agenda linking accelerated deactivation testing, machine-learning-guided feed classification and life-cycle assessment benchmarks aimed is proposed at meeting 2030 renewable-diesel targets.
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References
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TY - JOUR AU - Morales-Leal, Francisco PY - 2025 DA - 2025/10/24 TI - Bridging Refinery and Biorefinery: Modular Hydrotreating Pathways for Co-Processing Refractory Streams and Bio-Oils JO - Journal of Chemical Engineering and Renewable Fuels T2 - Journal of Chemical Engineering and Renewable Fuels JF - Journal of Chemical Engineering and Renewable Fuels VL - 2 IS - 1 SP - 1 EP - 5 DO - 10.62762/JCERF.2025.769005 UR - https://www.icck.org/article/abs/JCERF.2025.769005 KW - co-processing KW - hydrotreating KW - bio-oil KW - vacuum gas oil KW - modular refinery KW - catalyst deactivation AB - Integrating biomass-derived oils into existing petroleum refineries is one of the fastest routes toward large-scale deployment of renewable liquid fuels. Yet co-processing bio-oils with refractory fossil streams, such as vacuum gas oil, cycle oils or coker gas oils, poses persistent hurdles: their high oxygen content, thermal instability and heteroatom-rich matrices accelerate catalyst fouling and drive hydrogen consumption. This Perspective argues that a modular hydrotreating strategy, in which tailored pretreatment, grading and active catalyst beds are arranged as interchangeable cartridges, offers a pragmatic path to bridge refinery and biorefinery operations. Drawing from recent continuous slurry hydrocracking, fixed-bed co-hydrotreating and digital-twin studies, it outlines how modular bed architecture, advanced slurry catalysts and adaptive control schemes could unlock feed flexibility while extending catalyst life by ~40% and cutting greenhouse-gas footprints by ~25% relative to standalone units. Finally, a short-term R&D agenda linking accelerated deactivation testing, machine-learning-guided feed classification and life-cycle assessment benchmarks aimed is proposed at meeting 2030 renewable-diesel targets. SN - 3070-1058 PB - Institute of Central Computation and Knowledge LA - English ER -
@article{MoralesLeal2025Bridging,
author = {Francisco Morales-Leal},
title = {Bridging Refinery and Biorefinery: Modular Hydrotreating Pathways for Co-Processing Refractory Streams and Bio-Oils},
journal = {Journal of Chemical Engineering and Renewable Fuels},
year = {2025},
volume = {2},
number = {1},
pages = {1-5},
doi = {10.62762/JCERF.2025.769005},
url = {https://www.icck.org/article/abs/JCERF.2025.769005},
abstract = {Integrating biomass-derived oils into existing petroleum refineries is one of the fastest routes toward large-scale deployment of renewable liquid fuels. Yet co-processing bio-oils with refractory fossil streams, such as vacuum gas oil, cycle oils or coker gas oils, poses persistent hurdles: their high oxygen content, thermal instability and heteroatom-rich matrices accelerate catalyst fouling and drive hydrogen consumption. This Perspective argues that a modular hydrotreating strategy, in which tailored pretreatment, grading and active catalyst beds are arranged as interchangeable cartridges, offers a pragmatic path to bridge refinery and biorefinery operations. Drawing from recent continuous slurry hydrocracking, fixed-bed co-hydrotreating and digital-twin studies, it outlines how modular bed architecture, advanced slurry catalysts and adaptive control schemes could unlock feed flexibility while extending catalyst life by ~40\% and cutting greenhouse-gas footprints by ~25\% relative to standalone units. Finally, a short-term R\&D agenda linking accelerated deactivation testing, machine-learning-guided feed classification and life-cycle assessment benchmarks aimed is proposed at meeting 2030 renewable-diesel targets.},
keywords = {co-processing, hydrotreating, bio-oil, vacuum gas oil, modular refinery, catalyst deactivation},
issn = {3070-1058},
publisher = {Institute of Central Computation and Knowledge}
}
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